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File: //usr/share/webmin/postfix/help/dependent.html
<header>Sender dependent transport mappings</header>

The optional sender dependent addresses file allows the relay host for 
for outgoing SMTP connections to be set on a per-address or per-domain basis. The left
hand side of each entry can be either a full email address like
<tt>foo@bar.com</tt>, or just a domain like <tt>@bar.com</tt>. <p>

The right hand side must be in the format <i>transport:nexthop</i>. In the 
typical case where you want to relay mail via a specific mail server, 
<i>transport</i> should be <tt>smtp</tt> and <i>nexthop</i> the hostname or
IP address of the mail server. <p>

<hr>